Green Photochemistry: Sun-induced Aromatic Nucleophilic Substitution of Alkoxy Groups by Alkylamines

نویسندگان

  • Andrey V. Samoshin
  • Vyacheslav V. Samoshin
چکیده

Solar photochemistry was proved to be efficient for the nucleophilic substitution of alkoxy groups by amines in alkoxynitrobenzenes. The results of the sun-induced photochemical substitution were comparable to the outcome of the same reaction under irradiation by a low-pressure mercury lamp. Using 4’-nitrobenzo-15-crown-5 as a starting material we obtained a polyether amino alcohol a precursor for the regioselective synthesis of benzoazacrown ethers.

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تاریخ انتشار 2006